Theoretical evaluation of the deactivation mechanism of substituted dibenzothiophenes
G. Ramírez-Galicia, M. Poisot and H. Martínez-Pacheco
-
The chemical reactivity of peroxomolibdate catalyst was characterized through of hybrid orbitals analysis.
Reaction mechanism description of oxidative desulfurization of 4,6-dimethyldibenzothiophene was proposed using the peroxomolibdate catalyst.
The peroxo group formation as reactive specie in the catalyst is carried out in situ.
|