Cat24238 Vol. 23 No. 2 (2024)

Vol. 23, No. 2 (2024), Cat24238 https://doi.org/10.24275/rmiq/Cat24238

Fenton process by volcanic ash to eliminate aniline of aqueous solution from the dyeing of toquilla straw crafts

Authors

M. Vázquez-Romero, M. Abril-González, V. Pinos-Vélez, J. García-Zumalacarregui, D. Maldonado-Carchi, B. Miranda-Morales

Abstract

The toquilla straw hat is a cultural tourist attraction in the province of Azuay-Ecuador. Its production is carried out artisanally, with the dyeing process being one of the major problems due to the production of difficult-to-treat water that has an eco-toxicological impact on water-receiving bodies. A highly effective alternative for decoloring dyes is Advanced Oxidation Processes (AOP), the Fenton-like process that uses waste as catalysts as a source of iron that can be removed by filtration. In this work, the removal of dyes (red and black) in an aqueous solution used in the dyeing of handicrafts was carried out using ashes from the Cotopaxi volcano as a catalyst. The variable evaluated was the dye concentration reached when different amounts of ash and H2O2 were tested. Also, acute ecotoxicity tests were carried out with Daphnia Magna (D.M.) to determine its immobilization after 48 hours of exposure. For the black dye, a discoloration of 98.2 % was achieved after 48 hours of treatment using a Fe3+: H2O2 ratio of 2:2 (gml-1), while for the red dye in the same timeframe, a discoloration of 75.62 % was achieved with a Fe3+: H2O2 ratio of 2:4 (gml-1). Regarding the tests with D.M., they showed complete immobilization before the treatment and 0 % immobilization after the treatment, demonstrating water quality recovery.

Keywords

Fenton-like; volcanic ash, dyes.

References
Acero, J. A., Avendaño-Sánchez Amalia, & Bermúdez-Castañeda, A. (2023). Evaluación del proceso Fenton para el tratamiento de un agua sintética coloreada empleando calamina. Ingeniería y competitividad 25 (1): 1-23. Adewale G., Yusuf A., Balogun H.A., Sambudi N.S., Bilad M.R., Adeyemi I., Chakraborty S., & Curcio S. (2021). Recent advances in advanced oxidation processes for removal of contaminants from water: A comprehensive review. Process Safety and Environmental Protection 146: 220-56. Ángel-Hernández, B., F. Hernández-Aldana, G. Pérez Osorio, & Gutiérrez-Arias, JE Moisés. (2021). Municipal wastewater treatment by photocatalysis: comparison between UV lamp and solar radiation using TiO2 and ZnO/TiO2 synthesized catalysts. Revista Mexicana de Ingeniería Química 20 (3): Cat2438-Cat2438. Babuponnusami A., Sanyukta Sinha, Hridya Ashokan, Mathew V. Paul, Sai Prashant Hariharan, J. Arun, K. P. Gopinath, Quynh Hoang Le, & Arivalagan Pugazhendhi. (2023). Advanced oxidation process (AOP) combined biological process for wastewater treatment: A review on advancements, feasibility and practicability of combined techniques. Environmental Research, 116944. Chen, Q., Yuan Y., Zheying Z., Juan Z., & Zhao C. (2021). Long term catalytic activity of pyrite in Heterogeneous Fenton-like oxidation for the tertiary treatment of dyeing wastewater. Journal of Environmental Chemical Engineering 9 (4): 105730. Chu, J.-H., Jin-Kyu K., Seong-Jik P., & Chang-Gu L. (2020). Application of magnetic biochar derived from food waste in heterogeneous sono-Fenton-like process for removal of organic dyes from aqueous solution. Journal of Water Process Engineering 37: 101455. Contreras-Bustos, R., Cardenas-Mijangos, J., Dector-Espinoza, A., Rodriguez-García, A., Montoya-Herrera, L, & J. Jiménez-Becerril. (2020). Treatment of wastewater from the petrochemical industry by a chemical Fenton process. Revista Mexicana de Ingeniería Química 19 (2): 523-32. Galán, P.A. (2022). Valor Agregado al proceso de elaboración de objetos en paja toquilla y atractividad turística. Caso de estudio Economuseo Municipal Casa del Sombrero. Khan, W.U., Sirajuddin A., Yogesh D., & Sughosh M. (2023). A critical review of hazardous waste generation from textile industries and associated ecological impacts. Journal of the Indian Chemical Society 100 (1): 100829. Levenspiel, O. (2010). Ingeniería de las reacciones químicas. Reverté. Li, S., Yixin C., Min W., & Gaohua J. (2023). Toxic Effects of Methylene Blue on the Growth, Reproduction and Physiology of Daphnia magna. Toxics 11 (7): 594. Lin, J., Wenyuan Y., Ming X., Dong H. S., Jianquan L., Yinhua W., & Van der Bruggen B. (2023). Environmental impacts and remediation of dye-containing wastewater. Nature Reviews Earth & Environment, 1-19. Macías-Díaz, T.M., García-Ruiz J. G., & García Pedraza, L. (2023). Producción del Sombrero de Paja Toquilla en el contexto del desarrollo local comunitario. Revista de Ciencias Sociales 29 (8): 408-20. Nour, M. M., Maha A. T., & Hossam A. N. (2023=. Heterogeneous Fenton oxidation with natural clay for textile levafix dark blue dye removal from aqueous effluent. Applied Sciences 13 (15): 8948. Pinos, V. (2021). Predicción del valor de concentración letal media, LC50 y del nivel de toxicidad de compuestos orgánicos para Daphnia Magna usando algoritmos de aprendizaje automático supervisado. 2021. https://openaccess.uoc.edu/handle/10609/132526. Rojas-Valencia, O. G., M. Estrada-Flores, C. M., Reza-San-Germán, E.. Torres-Santillán, J. Hernández-Fuentes, & Ledezma-Martínez J. L. (2020). Effect of thermal treatment of activated carbon fiber felt for reuse in removal of methylene blue from a synthetic wastewater. Revista Mexicana de Ingeniería Química 19 (3): 1515-26. Saechan, C., Pongsakorn T., Supinya T., Sawitree H., Srinoun K., Aung Win T., Natta T., Watthanachai J., & Hansuk B. (2023). Degradation of Methylene Blue Using Fly Ash as a Heterogeneous Fenton Catalyst. Analytical Letters 56 (13): 2099-2112. https://doi.org/10.1080/00032719.2022.2155179. Sajid H., A. E., & Goi D. (2021). Catalytic activity of metals in heterogeneous Fenton-like oxidation of wastewater contaminants: a review. Environmental Chemistry Letters 19: 2405-24. Tavares, M.GR, Santos D., Tavares M.G., Duarte J., Meili L., Pimentel W., Tonholo J., & Zanta C. (2020). Removal of reactive dyes from aqueous solution by Fenton reaction: kinetic study and phytotoxicity tests. Water, Air, & Soil Pollution 231: 1-15. Tiya D.J., Lemougna P.N., Emadak A., Mbowou M.P., Laminsi S., & Melo U.C. (2018). Taking advantage of iron contained in natural volcanic ash for catalytic degradation of Rhodamine 6G. Journal of Applied Surfaces and Interfaces 3 (1-3). Thomas, N., Dionysios D. Dionysiou, & Suresh C. Pillai. (2021). Heterogeneous Fenton catalysts: A review of recent advances. Journal of Hazardous Materials 404: 124082. Uddin, M., Most Setara B., Ashraf M., Azad A., Adhikary A., & Sorowar M. (2023). Water and chemical consumption in the textile processing industry of Bangladesh. PLOS Sustainability and Transformation 2 (7): e0000072. Wang, C., Rong H., & Ruirui S. (2020). Green one-spot synthesis of hydrochar supported zero-valent iron for heterogeneous Fenton-like discoloration of dyes at neutral pH. Journal of Molecular Liquids 320: 114421. Yue, R., Bahareh R., Jalal R., Zhibin Y., Barbeau B., & Rahaman M. (2021). A photo-Fenton nanocomposite ultrafiltration membrane for enhanced dye removal with self-cleaning properties. Journal of Colloid and Interface Science 604: 458-68.

References

Acero, J. A., Avendaño-Sánchez Amalia, & Bermúdez-Castañeda, A. (2023). Evaluación del proceso Fenton para el tratamiento de un agua sintética coloreada empleando calamina. Ingeniería y competitividad 25 (1): 1-23.
Adewale G., Yusuf A., Balogun H.A., Sambudi N.S., Bilad M.R., Adeyemi I., Chakraborty S., & Curcio S. (2021). Recent advances in advanced oxidation processes for removal of contaminants from water: A comprehensive review. Process Safety and Environmental Protection 146: 220-56.
Ángel-Hernández, B., F. Hernández-Aldana, G. Pérez Osorio, & Gutiérrez-Arias, JE Moisés. (2021). Municipal wastewater treatment by photocatalysis: comparison between UV lamp and solar radiation using TiO2 and ZnO/TiO2 synthesized catalysts. Revista Mexicana de Ingeniería Química 20 (3): Cat2438-Cat2438.
Babuponnusami A., Sanyukta Sinha, Hridya Ashokan, Mathew V. Paul, Sai Prashant Hariharan, J. Arun, K. P. Gopinath, Quynh Hoang Le, & Arivalagan Pugazhendhi. (2023). Advanced oxidation process (AOP) combined biological process for wastewater treatment: A review on advancements, feasibility and practicability of combined techniques. Environmental Research, 116944.
Chen, Q., Yuan Y., Zheying Z., Juan Z., & Zhao C. (2021). Long term catalytic activity of pyrite in Heterogeneous Fenton-like oxidation for the tertiary treatment of dyeing wastewater. Journal of Environmental Chemical Engineering 9 (4): 105730.
Chu, J.-H., Jin-Kyu K., Seong-Jik P., & Chang-Gu L. (2020). Application of magnetic biochar derived from food waste in heterogeneous sono-Fenton-like process for removal of organic dyes from aqueous solution. Journal of Water Process Engineering 37: 101455.
Contreras-Bustos, R., Cardenas-Mijangos, J., Dector-Espinoza, A., Rodriguez-García, A., Montoya-Herrera, L, & J. Jiménez-Becerril. (2020). Treatment of wastewater from the petrochemical industry by a chemical Fenton process. Revista Mexicana de Ingeniería Química 19 (2): 523-32.
Galán, P.A. (2022). Valor Agregado al proceso de elaboración de objetos en paja toquilla y atractividad turística. Caso de estudio Economuseo Municipal Casa del Sombrero.
Khan, W.U., Sirajuddin A., Yogesh D., & Sughosh M. (2023). A critical review of hazardous waste generation from textile industries and associated ecological impacts. Journal of the Indian Chemical Society 100 (1): 100829.
Levenspiel, O. (2010). Ingeniería de las reacciones químicas. Reverté.
Li, S., Yixin C., Min W., & Gaohua J. (2023). Toxic Effects of Methylene Blue on the Growth, Reproduction and Physiology of Daphnia magna. Toxics 11 (7): 594.
Lin, J., Wenyuan Y., Ming X., Dong H. S., Jianquan L., Yinhua W., & Van der Bruggen B. (2023). Environmental impacts and remediation of dye-containing wastewater. Nature Reviews Earth & Environment, 1-19.
Macías-Díaz, T.M., García-Ruiz J. G., & García Pedraza, L. (2023). Producción del Sombrero de Paja Toquilla en el contexto del desarrollo local comunitario. Revista de Ciencias Sociales 29 (8): 408-20.
Nour, M. M., Maha A. T., & Hossam A. N. (2023=. Heterogeneous Fenton oxidation with natural clay for textile levafix dark blue dye removal from aqueous effluent. Applied Sciences 13 (15): 8948.
Pinos, V. (2021). Predicción del valor de concentración letal media, LC50 y del nivel de toxicidad de compuestos orgánicos para Daphnia Magna usando algoritmos de aprendizaje automático supervisado. 2021. https://openaccess.uoc.edu/handle/10609/132526.
Rojas-Valencia, O. G., M. Estrada-Flores, C. M., Reza-San-Germán, E.. Torres-Santillán, J. Hernández-Fuentes, & Ledezma-Martínez J. L. (2020). Effect of thermal treatment of activated carbon fiber felt for reuse in removal of methylene blue from a synthetic wastewater. Revista Mexicana de Ingeniería Química 19 (3): 1515-26.
Saechan, C., Pongsakorn T., Supinya T., Sawitree H., Srinoun K., Aung Win T., Natta T., Watthanachai J., & Hansuk B. (2023). Degradation of Methylene Blue Using Fly Ash as a Heterogeneous Fenton Catalyst. Analytical Letters 56 (13): 2099-2112. https://doi.org/10.1080/00032719.2022.2155179.
Sajid H., A. E., & Goi D. (2021). Catalytic activity of metals in heterogeneous Fenton-like oxidation of wastewater contaminants: a review. Environmental Chemistry Letters 19: 2405-24.
Tavares, M.GR, Santos D., Tavares M.G., Duarte J., Meili L., Pimentel W., Tonholo J., & Zanta C. (2020). Removal of reactive dyes from aqueous solution by Fenton reaction: kinetic study and phytotoxicity tests. Water, Air, & Soil Pollution 231: 1-15.
Tiya D.J., Lemougna P.N., Emadak A., Mbowou M.P., Laminsi S., & Melo U.C. (2018). Taking advantage of iron contained in natural volcanic ash for catalytic degradation of Rhodamine 6G. Journal of Applied Surfaces and Interfaces 3 (1-3).
Thomas, N., Dionysios D. Dionysiou, & Suresh C. Pillai. (2021). Heterogeneous Fenton catalysts: A review of recent advances. Journal of Hazardous Materials 404: 124082.
Uddin, M., Most Setara B., Ashraf M., Azad A., Adhikary A., & Sorowar M. (2023). Water and chemical consumption in the textile processing industry of Bangladesh. PLOS Sustainability and Transformation 2 (7): e0000072.
Wang, C., Rong H., & Ruirui S. (2020). Green one-spot synthesis of hydrochar supported zero-valent iron for heterogeneous Fenton-like discoloration of dyes at neutral pH. Journal of Molecular Liquids 320: 114421.
Yue, R., Bahareh R., Jalal R., Zhibin Y., Barbeau B., & Rahaman M. (2021). A photo-Fenton nanocomposite ultrafiltration membrane for enhanced dye removal with self-cleaning properties. Journal of Colloid and Interface Science 604: 458-68.